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STRUCTURES AND BONDS
By the end of this chapter, you should be able to:
Keywords
Competency: you will appreciate how atoms are composed of fundamental particles and how molecules and compounds are composed of atoms.
Introduction
If you look around your class, you will see different materials or substances. Are the different materials you see the same? Probably you will find out that they are different colours, texture, states and hardness. The different substances are formed when atoms of the same or different elements combine. This can occur between atoms of the same different kind. When atoms of the same elements combine, we get molecules of the elements. But when atoms different elements combine, compounds are formed.
But why do the elements combine? The elements which are able to combine lack the electronic stability which can be attained when they combine. The properties of Substances are dependent on the nature of bonds present between their atoms. In this chapter you will learn how atoms of same or different elements combine and what they form. You will also compare the properties of the substances formed through different types of bonding.
Have you thought about why different pure substances look different? The reason is that they are made up of different building blocks. The building blocks that make up matter are called atoms.
Atoms are the smallest, electrically neutral, indivisible particles of matter that can take part in a chemical reaction.
One of the early scientists called Dalton in this theory stated among others that atoms of the same element were exactly alike and different from atoms of other elements.
What are atoms made of? It is now known that atoms are made up of subatomic particles. The different in the particles may cause atoms of the same element to be different in some aspects. Activity 2.1 below, explores discoveries by different scientists about the structure of atoms. How do the theories help in understanding the structure of atoms?
Activity 2.1 exploring the discoveries related to atomic structure
What you need
Internet or any library books
What to do
In your groups, research for information about the discoveries related to the structure of atoms by the following scientists
Discussion
Atoms contain sub atomic particles
There are three types of subatomic particles inside an atom. These are protons, neutrons and electrons. The protons and neutrons are found in the central part of the atom called the nucleus. The nucleus is incredibly small and dense. Figure 2.1 shows an atom showing the location of subatomic particles and electrons.
Figure 2.1 Basic structure of an atom 1
The tiny electrons move around this nucleus in areas or orbits called energy levels (shells).
Activity 2.2 Modeling the basic structure of an atom
What you need
What to do
Discussion
you now know that the building blocks of matter are atoms. Look at figure 2.2 below showing pure magnesium ribbon and red phosphorus. Why do they look different?
Figure 2.2 A: Magnesium ribbon 1 Figure 2.2 B: Red phosphorus 1
The two substances look different because they are made up of different kinds of atoms. The different substances containing different kinds of particles in a pure substance are called elements. There are over 90 naturally occurring elements and you can name the common ones using activity 2.3 below.
Activity 2.3 Naming common elements in periodic table
What you need
What to do
In your groups, use the Periodic table, internet or any other book to find information about the common elements and their symbols
Discussion
Molecules
Do you recall what you learnt in senior one about molecules? When some atoms combine with one another, they form products called molecules. Molecules are small groups of atoms chemically combined. Molecules can be made up of the same or different elements. In the next activity, you will find out more about the structure of molecules.
Activity 2.4 Representing the structure of molecules using models
What you need
What to do
Discussion
Compounds
You have learnt that most materials we use in everyday life are compounds. Figure 2.3 shows a woman fetching water in lake Albert in western Uganda. Water is example of a compound. It is made up of hydrogen and oxygen atoms combined chemically.
Figure 2.3: Woman fetching water. Water is a compound 1
Substances which are made up of two or more different elements are called compounds.
Compounds are pure substances formed when two or more elements of different kinds chemically combine together.
Can you identify any other examples of compounds? Activity 2.5 will help you to understand the different compounds.
Activity 2.5 Modelling the structure of compounds
What you need
What to do
Discussion
In senior two, we learnt that elements contain sub-atomic particles. Can you recall the subatomic particles that form atoms? The subatomic particles include protons, neutrons and electrons. Figure 2.4 shows a model diagram of one atom of carbon indicating the atom of carbon indicating the location of subatomic particles. As already learnt, the sub atomic particles differ in charge and mass.
Figure 2.4: Structure of the carbon atom showing the particles 1
Different atoms contain a different number of sub-atomic particles. In the next activity you will model different atoms and show their subatomic particles.
Activity 2.6 Modelling atoms with different subatomic particles
What you need
Internet or library resources
Materials from the environment
What to do
Discussion
The sub-atomic particles in atoms differ in their properties particularly the mass and charge. Figure 2.6 shows a model of a nitrogen atom showing the different charges on the subatomic particles.
Figure 2.6: Model of a nitrogen atom showing the charges on particles 1
What are the properties of the particles? In the next activity you will show the difference in properties between the three types of sub-atomic particles.
Activity 2.8 identifying properties of sub-atomic particles
What you need
Internet or library resources
What to do
Search for information about properties of subatomic particles
Discussion
You now know that elements are arranged in the periodic table according to their atomic numbers. Do you recall the meaning of atomic number? The atomic number Z of an element is the number of protons the atom of an element. Thus, different atoms have different atomic numbers.
Figure 2.7 Representing atomic number and mass number for helium1
The mass number (A) is the number of protons and neutrons in the atom of an element. Since the protons and neutrons reside in the nucleus of an atom, the mass number can also be called the nucleon number. In activity 2.9, you will use the periodic table to write the numbers and mas numbers of different elements.
Activity 2.9 Exploring atomic numbers and mass numbers of different of different elements
What you need
Copy of periodic table, internet or books
What to do
Discussion
Relationship between mass number and atomic number
Is there a relationship between a mass number and atomic number? You have earnt that the number of protons in an atom is equal to the number in electrons. You are also aware that the number is the sum of protons and electrons. Mathematically?
Protons + neutrons=mass number
We can use the information to solve the problems involving the particles in an atom.
Worked example 2.1 calculating mass number
What is the mass number of atom which contains 14neutrons and 13 protons in its nucleus?
The mass number is 27.
Exercise 2.1
What is the mass number of an atom which contains 18 neutrons and 17 protons in its nucleus?
Worked example 2.2 Calculating the number of neutrons
What is the number of neutrons in an atom mass number is 31 and the number of protons is 15?
The neutron number is 20.
Exercise 2.2
What is the neutron number of an atom which contains 56 protons and has mass number 116?
Isotopes
Dalton in this theory stated that all elements are identical. Do you agree with this assertion? It is possible to find atoms of the same element with the same atomic number but different mass numbers. One examples of an element that has isotopes is carbon. Carbon has two known isotopes. One with a mass number of 12 while the other has a mass of 14. The two carbon atoms differ in the number of neutrons in their nuclei. One other element that has isotopes is hydrogen. Figure 2.8 below shows models of the isotopes of hydrogen.
Figure 2.8: Isotopes of hydrogen 1
What difference can you see between the isotopes of hydrogen?
Isotopes are atoms of the same element with the same atomic number but different mass number.
In activity 2.10, you will explore the different elements which have isotopes.
Activity 2.10 identifying isotopes
What you need
Internet or library resources
What to do
In your groups, search for information about isotopes
Discussion
Relative atomic mass
Figure 2.9 below shows a balance used to weigh different merchandise in our shops. To weigh for example sugar, you have to place a standard stone and relate it with an equal mass of sugar.
Figure 2.9: Weighing balance 1
Similarly, because the actual masses of atoms are very small, we measure them against a standard mass. The mass of carbon-12 atom, 12C6 is used as the standard atom against which the masses of other atoms are compared.
The relative atomic mass of an element is the average mass of its atoms, compared to 1/12th the mass of a carbon-12 atom Sloper.
Since some elements have isotopes, the relative atomic mass, A, of an element is calculated from the mass numbers of its isotopes and their abundance. The relative atomic mass of an element is the average contribution of the isotopes. It is given by:
RAM=Isotopes mass x percentage abundance of the isotope( ∑means sum of the elements)
Worked example 2.3 Calculating relative atomic mass
Natural chlorine consists of 75% chlorine -37 and 25% chlorine-35. What is the relative atomic mass of chlorine?
Contribution from chlorine-35=35x 75/100= 26.25
Contribution from chlorine-37=37x 25/100=9.25
Relative atomic mass= 26.25+9.25=35.5
Exercise 2.3
The table shows the mass numbers and abundances of naturally occurring copper isotopes.
Why do atoms combine?
You have observed that the materials in our midst are predominantly made up of more than atom combined. Why do the atoms combine? To understand why chemical bonds form, consider the common compound known as water (H2O). It consists of two hydrogen (H) atoms and one oxygen (O) atom. As you can on the left side of the figure 2.10 below, each hydrogen atom has just one electron, which is also its only valence electron. The oxygen atom has six electrons in the outer energy level but only 2 are unpaired.
Figure 2.10: Demonstrating formation of a water molecule1
In the water molecule on the right in the Figure 2.10 above, each hydrogen atom shares a pair of electrons with the oxygen atom. By sharing electrons, each atom has electrons available to fill its outer energy level. In the water molecule, each of the hydrogen atoms has a pair of shared electrons making its outer energy level fully filled with electrons. The oxygen atom has a total of eight electrons in its outer shell, so its outer energy level is also full. A full outer energy level is the most stable possible arrangement of electrons. It explains why elements form chemical bonds with each other.
Outer electrons are responsible for bonding
You have already learnt that atoms combine to attain a fully filled outer energy level. Which electrons are involved in chemical bonding? Electrons in inner energy levels occupy a completely full energy level. In addition, they are not accessible or available to combine. Therefore, it is the outer electrons which undergo chemical bonding to be fully filled by the electrons. The outer electrons of an atom are called valency electrons. Figure 2.11 below shows the valence electrons in a carbon atom.
Figure 2.11: valence electrons in the carbon atom 1
In activity 2.11, you will represent structures of atoms and show valence electrons.
Activity 2.11 Representing electronic structures of atoms by showing valence electrons
What you need
What to do
Discussion
Atoms can lose or gain electrons to form ions
You have learnt valency electrons are responsible for chemical bonding. You have also learnt that atoms combine in order to gain the stable electronic structure of noble gases. But how can this structure be attained? The noble gas structure is attained by loss or gain of electrons, ions are formed. The figures below (2.12 and 2.13) show an illustration of loss and gain of electrons by atoms. Note the noble gas structure attained in each case.
Figure 2.12: Formation of a sodium ion 1
Similarly, the formation of a fluoride ion involves gain of an electron to form a negative ion.
Figure 2.13: Formation of chloride ion. 1
Activity 2.12 Demonstrating loss and gain of electrons by atoms
What you need
What to do
Discussion
How do atoms make molecules and compounds? Typically, atoms and molecules join together in such a way that they lose their identities as elements and adopt a new identity as molecules and compounds. This process is called chemical bonding. The three common types of chemical bonds include covalent, ionic, and metallic bonds. Each type of bonding is described below.
Ionic bonding
Chemical bonding takes place between electrons in the outer energy level. You also know that bonding takes place for the atoms to be stable. Stability can be attained if atoms lose gain or share their valence electrons. Ionic bonding takes place when atoms are transferred from one atom to another.
An ionic (electrovalent) bond is formed by the transfer of electrons between atoms.
Figure 2.14 below shows loss and gain of electrons in the formation of sodium chloride.
Figure 2.14 Formation of sodium chloride 1
As show in figure 2.14, the sodium atom loses its outer electron to the chlorine atom forming a positive charge while chlorine forms a negative charge. The two oppositely charged ions attract each other and combine chemically to form sodium chloride. You can illustrate the bonding between atoms by carrying out activity 2.13
Activity 2.13 Drawing and modeling ionic compounds
What you need
What to do
Discussion
Covalent Bonding
You have already learnt that ionic compounds are formed by the transfer electrons. One other type of bonding is covalent bonding. Unlike ionic bonding, covalent bonding involves the sharing of electrons between atoms. Contrary to ionic bonding where the atoms must be metals and non-metals, covalent bonding takes place between non-metals. One example of covalent bonding is the formation of hydrogen chloride molecule (Figure 2.15)
Figure 2.15: Formation of hydrogen chloride molecule1
You note that during covalent bond formation, the valence electrons of the two atoms are shared thus forming the hydrogen chloride molecule. you can this example to illustrate the formation of covalent bonds between other atoms by doing activity 2.14.
Activity 2.14 Drawing and modelling formation of covalent bonds
What you need
What to do
Discussion
You have learnt that ionic compounds are formed by transfer of electrons while covalent substances are formed by the sharing of electrons. Thus, the properties for the different compounds produced in different ways must be different. In activity 2.15, you compare the properties of compounds with the two types of bonds.
Activity 2.15 comparing melting points and solubility of covalent and ionic substances.
What you need
Caution: observe all safely precautions when using the Bunsen burner or any source of heat to avoid burns.
What to do
Discussion
Electrical conductivity is the ability of a substance to conduct electricity. Do you recall from senior 2 that metals conduct electricity? Not only metals conduct electricity. Many ionic and same covalent substances conduct electricity. Also, the physical state of the substance can affect its ability to conduct electricity. For example, sodium hydrogen carbonate (baking powder) figure 2.16 cannot conduct electricity in solid state.
Figure 2.16: Baking powder does not conduct electricity1
However, it is good conductor of electricity when dissolved in water. In the next activity, you will find out whether ionic substances conduct electricity and in what form.
Activity 2.16 Investigating conductivity and physical state of covalent and ionic substances.
What you need
What to do
Figure 2.17: Conducting of ionic compounds 1
Discussion
Metallic bonding
You are probably familiar with metals such as copper, iron, aluminum and silver. But do you know what an element a metal? One is that all metals give up electrons easily. In a metal structure, there is only one kind properties.
Aluminum copper wire cast iron utensils
Figure 2.18: Metals contain the metallic bonds1
Therefore, the electrons cannot be donated since the pushing capacity is the same. In metals, the valence electrons move freely throughout the structure (they are delocalized) forming a mobile ‘sea’ of electrons. Figure 2.19 illustrates a model of the electrons surrounding the metal cations.
Figure 2.19: Model of metallic structure showing free electrons 1
The positive ions maintain the electrons in the space between the different ions. The solid structure of atoms can be modelled to fully understand this relationship between metal cations and their electrons.
Activity 2.17 drawing and modelling the structure of metals.
What you need
What to do
Discussion
ACTIVITY OF INTERGRATION
You have been employed as a plumber in a very busy hotel. The hotel manager has narrated to you that the biggest problem in the hotel include smell from the dumping place, blockage of toilets and dirt in the sinks.
He wants you investigate the reasons and suggest solutions to the different problems faced by the hotel. Write a report to the manager explaining the causes of the problems and solutions to solve them.
Figure 2.18: Water flowing into a sink 1
Your report should include:
CHAPTER SUMMARY
REVISION EXERCISE
b. Compare the properties of covalent and ionic compounds
(a) metals are good conductors of electricity and heat.
(b) ionic compounds do not conduct electricity in solid state.
(c) covalent compounds are insoluble in water.
(a) Mention four similarities between the metals.
(b) Explain why the similarities exist.