The following is a list of specific heat capacities for a few metals.
Ccopper=0.385
Ciron=0.444
Csilver=0.240
Caluminum=0.900
A 50g sample of an unknown metal is heated with 800 joules. If the temperature of the metal increases by 41.6oC, what is the identity of the unknown metal?
Possible Answers:
Copper
Iron
Aluminum
Silver
Correct answer:Copper
Explanation:We need to find the specific heat of the unknown sample of metal in order to locate it on the list. We can do this by using the equation that allows us to determine the specific heat capacity of an element.
q=mCΔT
Since we know the change in temperature, we can simply plug in the values and solve for the value of C.
800J=(50g)C(41.6oC)
C=0.385
Going back to the list, we see that this is the specific heat capacity for copper, so we confirm that the unknown metal is copper.
In which instance would a bomb calorimeter be more useful than a coffee-cup calorimeter?
Possible Answers:
None of the above
When measuring the specific heat of water vapor
When measuring the heat capacity of a solid
When measuring the mass of a substance
Correct answer:When measuring the specific heat of water vapor
Explanation:Bomb calorimeters are most useful when dealing with a gas, because they can operate well at high pressures. Coffee-cup calorimeters are not useful when water begins to boil, producing vapor.
How much heat does it take to heat 100g ice at 0C to boiling point?
Cice= 2.1 J/goC
Cwater= 4.2 J/goC
ΔHvap= 2260 J/g
ΔHfus=334 J/g
Possible Answers:
75.4 kJ
300.5 kJ
42 kJ
55.4 kJ
33.4 kJ
Correct answer:75.4 kJ
Explanation:You need heat for the phase change, using the enthalpy of fusion (100g*334 J/g = 33400 J). Add to this the heat to get to boiling point using the specific heat of water (100g*100C*4.2 J/goC = 42000 J). Totalling 75400 J (75.4 kJ)
The specific heat capacity of an unknown liquid is 0.32Jkg⋅K. The density of the liquid is 0.0321gmL If a chemist applies 243 J of heat to 300 mL of this liquid starting at 27.1∘C, what is the final temperature?
Possible Answers:
270.1∘C
None of the available answers
2700.1∘C
78882K
78882∘C
Correct answer:78882∘C
Explanation:First we will determine the mass of the liquid:
300mL×0.0321g1mL=9.63g
Now we will examine the relationship between heat and specific heat capacity:
Q=cmΔT
Where Q is heat in Joules, c is the specific heat capacity, m is the mass and ΔT is the change in temperature. We can rearrange this
ΔT=Qcm
ΔT=243J0.32J⋅kg−1⋅K−10.00963kg=78855K
If we begin at 27.1∘C, we will end at 78882∘C
A 50g sample of a metal was heated to 95oC then quickly transferred to an insulated container containing 50g of H2O at 25oC. The final temperature of the H2O was 30oC.
Which of the following can be concluded?
Possible Answers:
The metal lost an amount of thermal energy that was more than the amount of thermal energy gained by the water
The specific heat of the metal is greater than that of the water
The water gained an amount of thermal energy that was more than the amount of thermal energy lost by the metal
None of the other answers
The specific heat of the water is greater than that of the metal
Correct answer:The specific heat of the water is greater than that of the metal
Explanation:When the heated metal is placed in the container of the cooler water there will be a transfer of thermal energy from the metal to the water. This transfer will occur towards an equilibrium of thermal energy in the water and in the metal. Thus we can conclude that the amount of thermal energy lost by the metal will equal the amount of thermal energy gained by the water. However we notice that the water increases by only 5oC and the metal decreases by 65oC. This is becasue of the difference of the specific heats of these substances. The specific heat capacity of a substance is the heat required to increase the temperature of 1g of a substance by 1oC. The metal can be conluded to have a smaller specific heat than the water because the same amount of energy transfer led to a much larger change in termperature for the metal as compared to the water.
Which of the following is the correct molar specific heat of water used when making calculations involving a calorimeter?
Possible Answers:
4.184 J/gK
418.4 J/gK
41.84 J/gK
0.4184 J/gK
Correct answer:4.184 J/gK
Explanation:4.184 J/gK is the cited value for the specific heat of water and should be memorized. This is used during calorimeter calculations, specifically when using the equation q= mc delta(T).
Cice=0.5calg∘C
Cwater=1.0calg∘C
ΔHfusion=80calg
How much energy is needed to raise the temperature of five grams of ice from −10oC to 35oC?
Possible Answers:
200cal
600cal
280cal
120cal
Correct answer:600cal
Explanation:This question involves the total energy needed for three different processes: the temperature raise from −10oC to 0oC, the melting of the ice, and the temperature raise from 0oC to 35oC. For the first and third transitions we will use the equation q=mCΔT. For the melting of ice, we will use the equation q=mΔHfusion.
1. q=miceCiceΔT=(5g)(0.5calg∘C)(10∘C)=25cal
2. q=mΔHfusion=(5g)(80calg)=400cal
3. q=mwaterCwaterΔT=(5g)(1.0calg∘C)(35∘C)=175cal
Finally, we will need to sum the energy required for each step to find the total energy.
25cal+400cal+175cal=600cal
You want to prepare a cup of tea. To do so, you pour 100mL of tap water at 200C in a cup that does not absorb microwave radiation and heat it in a microwave oven at 700W of power. If you assume a density of 1.00gmL for the water and know that its specific heat capacity is 4.184JgoC , what time do you need to set in the microwave oven to heat the water to 60oC?
Possible Answers:
23.9s
40s
24s
700W of power is not enough to heat that a amount of water to the desired temperature
Correct answer:23.9s
Explanation:Q=m⋅C⋅ΔT
Since the density of water is 1.00gmL, the mass of 100mL is 100g. Plug in known values to the equation and solve.
100g⋅4.184JgoC⋅(60−20)oC=16736J
Use the formula below to find the time needed to heat up the sample of water in the microwave:
P=ΔWΔt
Δt=16736J700W=23.9s
Our answer must contain three significant figures.
How much heat is needed to raise 5 grams of aluminum by 20oC?
Caluminum=0.900Jg⋅oC.
Possible Answers:
9J
90J
120J
45J
Correct answer:90J
Explanation:To find the amount of heat needed to change the temperature of a given material by a certain amount, we’ll need to use the equation for specific heat. The specific heat capacity of a compound represents the amount of energy necessary to raise 1 gram of that substance by 1oC.
q=mCΔT
q=(5grams)(0.900Jg⋅oC)(20oC)=90J
A 20g sample of iron at a temperature of 120oC is placed into a container of water. There are 300 milliliters of water in the container at a temperature of 30oC.
Ciron=0.444Jg∘C
Cwater=4.184Jg∘C
ρwater=1gmL
What is the final temperature of the water?
Possible Answers:
114.0∘C
34.87∘C
30.63∘C
36.0∘C
32.71oC
Correct answer:30.63∘C
Explanation:There are two things to note before solving for the final temperature.
1. The density of water allows us to say that 300 milliliters of water is the same thing as 300 grams of water.
300mL∗1g1mL=300g
2. Since the heat from the iron is being transferred to the water, we can say that the heat transfer is equal between both compounds. Since the heat is conserved in the system, we can set the two equations equal to one another.
q=mCΔT
qi=qw→miCiΔT=mwCwΔT
miCi(Tinitial−Tfinal)=mwCw(Tfinal−Tinitial)
Notice how the change in temperature for iron has been flipped in order to avoid a negative number.
(20g)(0.444Jg∘C)(120∘C−Tf)=(300g)(4.184Jg∘C)(Tf−30∘C)
Tf=30.63∘C
Because water has a much higher heat capacity compared to iron, the temperature of the water is not changed significantly.
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