CALORIMETRY ASSIGNMENT

Calorimetry, Specific Heat, And Calculations

The following is a list of specific heat capacities for a few metals.

Ccopper=0.385

Ciron=0.444

Csilver=0.240

Caluminum=0.900

A 50g sample of an unknown metal is heated with 800 joules. If the temperature of the metal increases by 41.6oC, what is the identity of the unknown metal?

Possible Answers:

Copper

Iron

Aluminum

Silver

Correct answer:Copper

Explanation:We need to find the specific heat of the unknown sample of metal in order to locate it on the list. We can do this by using the equation that allows us to determine the specific heat capacity of an element.

q=mCΔT

Since we know the change in temperature, we can simply plug in the values and solve for the value of C.

800J=(50g)C(41.6oC)

C=0.385

Going back to the list, we see that this is the specific heat capacity for copper, so we confirm that the unknown metal is copper.

Example Question #1 : Calorimetry, Specific Heat, And Calculations

In which instance would a bomb calorimeter be more useful than a coffee-cup calorimeter?

Possible Answers:

None of the above

When measuring the specific heat of water vapor

When measuring the heat capacity of a solid

When measuring the mass of a substance

Correct answer:When measuring the specific heat of water vapor

Explanation:Bomb calorimeters are most useful when dealing with a gas, because they can operate well at high pressures. Coffee-cup calorimeters are not useful when water begins to boil, producing vapor.

Example Question #1 : Calorimetry, Specific Heat, And Calculations

How much heat does it take to heat 100g ice at 0C to boiling point?

Cice= 2.1 J/goC

Cwater= 4.2 J/goC

ΔHvap= 2260 J/g

ΔHfus=334 J/g

Possible Answers:

75.4 kJ

300.5 kJ

42 kJ

55.4 kJ

33.4 kJ

Correct answer:75.4 kJ

Explanation:You need heat for the phase change, using the enthalpy of fusion (100g*334 J/g = 33400 J). Add to this the heat to get to boiling point using the specific heat of water (100g*100C*4.2 J/goC = 42000 J). Totalling 75400 J (75.4 kJ)

Example Question #1 : Calorimetry, Specific Heat, And Calculations

The specific heat capacity of an unknown liquid is 0.32JkgK. The density of the liquid is 0.0321gmL If a chemist applies 243 J of heat to 300 mL of this liquid starting at 27.1C, what is the final temperature?

Possible Answers:

270.1C

None of the available answers

2700.1C

78882K

78882C

Correct answer:78882C

Explanation:First we will determine the mass of the liquid:

300mL×0.0321g1mL=9.63g

Now we will examine the relationship between heat and specific heat capacity:

Q=cmΔT

Where Q is heat in Joules, c is the specific heat capacity, m is the mass and ΔT is the change in temperature. We can rearrange this

ΔT=Qcm

ΔT=243J0.32Jkg1K10.00963kg=78855K

If we begin at 27.1C, we will end at 78882C

Example Question #1 : Calorimetry, Specific Heat, And Calculations

A 50g sample of a metal was heated to 95oC then quickly transferred to an insulated container containing 50g of H2O at 25oC.  The final temperature of the H2O was 30oC.

Which of the following can be concluded?

Possible Answers:

The metal lost an amount of thermal energy that was more than the amount of thermal energy gained by the water

The specific heat of the metal is greater than that of the water

The water gained an amount of thermal energy that was more than the amount of thermal energy lost by the metal

None of the other answers

The specific heat of the water is greater than that of the metal

Correct answer:The specific heat of the water is greater than that of the metal

Explanation:When the heated metal is placed in the container of the cooler water there will be a transfer of thermal energy from the metal to the water.  This transfer will occur towards an equilibrium of thermal energy in the water and in the metal. Thus we can conclude that the amount of thermal energy lost by the metal will equal the amount of thermal energy gained by the water.  However we notice that the water increases by only 5oC  and the metal decreases by 65oC.  This is becasue of the difference of the specific heats of these substances.  The specific heat capacity of a substance is the heat required to increase the temperature of 1g of a substance by 1oC. The metal can be conluded to have a smaller specific heat than the water because the same amount of energy transfer led to a much larger change in termperature for the metal as compared to the water.

Example Question #1 : Calorimetry, Specific Heat, And Calculations

Which of the following is the correct molar specific heat of water used when making calculations involving a calorimeter?

Possible Answers:

4.184 J/gK

418.4 J/gK

41.84 J/gK

0.4184 J/gK

Correct answer:4.184 J/gK

Explanation:4.184 J/gK is the cited value for the specific heat of water and should be memorized. This is used during calorimeter calculations, specifically when using the equation q= mc delta(T).

Example Question #1 : Calorimetry, Specific Heat, And Calculations

Cice=0.5calgC

Cwater=1.0calgC

ΔHfusion=80calg

How much energy is needed to raise the temperature of five grams of ice from 10oC to 35oC?

Possible Answers:

200cal

600cal

280cal

120cal

Correct answer:600cal

Explanation:This question involves the total energy needed for three different processes: the temperature raise from 10oC to 0oC, the melting of the ice, and the temperature raise from 0oC to 35oC. For the first and third transitions we will use the equation q=mCΔT. For the melting of ice, we will use the equation q=mΔHfusion.

1. q=miceCiceΔT=(5g)(0.5calgC)(10C)=25cal

2. q=mΔHfusion=(5g)(80calg)=400cal

3. q=mwaterCwaterΔT=(5g)(1.0calgC)(35C)=175cal

Finally, we will need to sum the energy required for each step to find the total energy.

25cal+400cal+175cal=600cal

Example Question #1 : Calorimetry, Specific Heat, And Calculations

You want to prepare a cup of tea. To do so, you pour 100mL of tap water at 200C in a cup that does not absorb microwave radiation and heat it in a microwave oven at 700W  of power. If you assume a density of  1.00gmL  for the water and know that its specific heat capacity is 4.184JgoC , what time do you need to set in the microwave oven to heat the water to 60oC?

Possible Answers:

23.9s

 40s

24s

700W of power is not enough to heat that a amount of water to the desired temperature

Correct answer:23.9s

Explanation:Q=mCΔT

Since the density of water is 1.00gmL, the mass of 100mL is 100g. Plug in known values to the equation and solve.

100g4.184JgoC(6020)oC=16736J

Use the formula below to find the time needed to heat up the sample of water in the microwave:

P=ΔWΔt

Δt=16736J700W=23.9s

Our answer must contain three significant figures.

Example Question #1 : Calorimetry, Specific Heat, And Calculations

How much heat is needed to raise 5 grams of aluminum by 20oC?

Caluminum=0.900JgoC.

Possible Answers:

9J

90J

120J

45J

Correct answer:90J

Explanation:To find the amount of heat needed to change the temperature of a given material by a certain amount, we’ll need to use the equation for specific heat. The specific heat capacity of a compound represents the amount of energy necessary to raise 1 gram of that substance by 1oC.

q=mCΔT

q=(5grams)(0.900JgoC)(20oC)=90J

Example Question #7 : Calorimetry, Specific Heat, And Calculations

A 20g sample of iron at a temperature of 120oC is placed into a container of water. There are 300 milliliters of water in the container at a temperature of 30oC.

Ciron=0.444JgC

Cwater=4.184JgC

ρwater=1gmL

What is the final temperature of the water?

Possible Answers:

114.0C

34.87C

30.63C

36.0C

32.71oC

Correct answer:30.63C

Explanation:There are two things to note before solving for the final temperature.

1. The density of water allows us to say that 300 milliliters of water is the same thing as 300 grams of water.

300mL1g1mL=300g

2. Since the heat from the iron is being transferred to the water, we can say that the heat transfer is equal between both compounds. Since the heat is conserved in the system, we can set the two equations equal to one another.

q=mCΔT

qi=qwmiCiΔT=mwCwΔT

miCi(TinitialTfinal)=mwCw(TfinalTinitial)

Notice how the change in temperature for iron has been flipped in order to avoid a negative number.

(20g)(0.444JgC)(120CTf)=(300g)(4.184JgC)(Tf30C)

Tf=30.63C

Because water has a much higher heat capacity compared to iron, the temperature of the water is not changed significantly.

Mugisa Geofrey and SOLOMON TATWEBWA

Mugisa Geofrey Zziwa is a learning facilitator with Ultimate MultiMedia Consult. With knowledge of the following topics:  Digital Pedagogy training or digital teaching skills, how to integrate ICT in teaching.  Journalism and the Internet/Computers (How internet helps journalism)  Basic web design & CMS and Multimedia Content publishing  Digital security and safety basics for journalists  Best practices for ensuring safety online  Data Mashups  Collaborative digital content development tools  Live streaming and Live reporting  Immersive Storytelling tools and practices  Among others I have conducted a number of trainings which include: • Multimedia Journalism and Digital Safety training for university Students held in Makerere University, Kampala International University and Cavendish University and sponsored by the American Embassy Uganda. • Digital Pedagogy training for Science Technology Engineering and Mathematics (STEM) Teachers held in Iganga Girls SSS in Iganga District for Eastern region Uganda, St. Maria Gorretti in MPigi District for Central region Uganda, and Teso College ALOET for the Karamoja region Uganda. Sponsored by Forum for African Women Educationalists Uganda (FAWEU) Training Teachers on integration of ICT in teaching and delivering lessons to students. • Digital Pedagogy at American Center for Teachers by Teachers In Need (TIN) Uganda. • Facilitator on Digital Pedagogy with ICT Teachers Association Uganda (ITAU) at American Center, Kyebambe Girls SSS in FortPortal for western region Uganda, Dr. Obote College Boro Boro Lira for Nothern Region Uganda.

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